Interweaving the relative time scale with the atomic time scale poses certain problems because only certain types of rocks, chiefly the igneous variety, can be dated directly by radiometric methods; but these rocks do not ordinarily contain fossils.
This just goes to show that just because independent estimates of age seem to agree with each other doesn't mean that they're correct - despite the fact that this particular argument is the very same one used to support the validity of radiometric dating today.
Potassium - Argon and Argon - Argon dating are based on the current understanding that radioactive Potassium-40 decays to the stable form, Argon-40 with a half-life of approximately 1.25 billion years.
There are some circumstances that can affect this rate such as magnetic fluctuations etc...
There is perhaps no beguilement more insidious and dangerous than an elaborate and elegant mathematical process built upon unfortified premises." - Chamberlain 1899b:224Following the discovery of radioactivity by Becquerel (1896), the possibility of using this phenomenon as a means for determining the age of uranium-bearing minerals was demonstrated by Rutherford (1906).
One year later Boltwood (1907) developed the chemical U-Pb method. By combining Von Weizsacker’s argon abundance arguments with Kohlhorster’s observation that potassium emitted gamma-radiation, Bramley (1937) presented strong evidence that potassium underwent dual decay.